

What
about that TURQUOISE HAIR?
.... or Good Grief Goldilocks
Goin' Green!
What's all
this nonsense about green hair being caused by chlorine?
This fable has been around nearly as long as the one about
that water additive causing pool pee to turn red. But blondies'
curls do turn green in chlorinated water you say... Well,
we're here to tell you it has nothing to do with the chlorine.
We know the offender, and its name is... copper!
Let's start by insisting that
a short series of events must occur before hair, or anything
else in the pool, can turn green. Water must be allowed
to become aggressive (negative calcium-saturation-index
numbers); it must dissolve some metallic copper, it must
have sulfates in it, then later high pH conditions must
prevail (values above pH 8.3) to precipitate the stuff that
the water had previously dissolved. This last step can happen
in the water itself, on the plaster or, yep, in the hair!
Let's get a little critical
here. The color in question cannot manifest itself without
the aforementioned copper in the water, then in the hair
yet neither should be the case in a well-managed pool. If
copper is present in the water, that's the pool operator's
fault and the pool operator's problem. Copper simply shouldn't
be in there. If it is, somebody got it there; neither make-up
(city) or natural (well) water has copper in it, so we are
told by water-plant engineers and geologists.
But liquid pool heater is
an all-too-frequent part of swimming-pool water because
of sloppy water management. Copper pipes (heaven forbid)
and bronze impellers contribute along with the heater's
internal elements, as aggressive water will stop at nothing
until it's satisfied. Since pH is by far the most influential
variable in the CSI, one could safely say that temporary
low pH caused by acidic sanitizers or by excessive pH correction
with acid is the primary "cause" for this aggressive
water. Such water achieves this fulfillment by taking on
every metal and mineral in its environment, and that includes
generous portions of the pool-system's copper.
Meanwhile, everybody's hair
absorbs this copper-bearing water. Yes, the black-, brown-
and red-headed kids as well as the blondies take on this
still invisible dissolved metal. Then the second influence
finishes the job: they shampoo. As all normal shampoos have
high pH values, the dreaded precipitation occurs. Visible
copper (oxide or sulfate) appears, providing that lovely
shade of turquoise.
But only the blond-haired
swimmers look like Heavy Metal groupies, since there is
little pigment there to mask the green effect. And if the
hair has been bleached blond you can expect near' twice
the effect, as damaged or stripped hair has much more absorbency
to hold the copper-bearing water.
What can the swimmers do?
Rinsing the hair thoroughly and towel drying rather than
letting the water evaporate with contents left behind seems
somewhat effective. Shampooing with "swimmers' shampoo"
helps because it has an intentionally lowered pH to avoid
precipitation. The best plan, of course, is to swim in,
or operate, a well-managed pool with perfect, copper-free
water.
If your swimmers are already
affected, you can assure them that the color will fade after
multiple shampoos. In the meantime, you may want to suggest
that they join a punk-rock band.
~ kw
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